TR32-Database: Database of Transregio 32

[642] - Analysis of Multisite 2D Relaxation Exchange NMR

All available metadata of the dataset are listed below. Some features are available, e.g. download of dataset or additional description file.

Features
Citation
Van Landeghem, M. ., Haber, A., D'Espinose de Lacaillerie, J., Blümich, B., 2010. Analysis of Multisite 2D Relaxation Exchange NMR. Concepts in Magnetic Resonance Part A, 36 (3), 153 - 169. DOI: 10.1002/cmr.a.20157.
Identification
Title(s):Main Title: Analysis of Multisite 2D Relaxation Exchange NMR
Description(s):Abstract: Two-dimensional (2D) relaxation exchange nuclear magnetic resonance (NMR) is in many ways similar to 2D frequency exchange NMR, except that the encoding times are comparable to the exchange time. This fact prevents the straightforward analysis of the cross-peak intensities in terms of joint probability densities, and quantitative information and understanding can only be obtained by comparison with simulated spectra. Based on simulations, an explanation is proposed as to why interference between relaxation and exchange may lead to asymmetric 2D exchange maps when exchange occurs between more than two sites. Practically, retro-fitting a simulated data set to an experimental one is shown to allow for the determination of the experimental relaxation and exchange parameters. This point is illustrated by studying a two-site model system consisting of interstitial water exchanging within a pack of spherical silica particles.
Identifier(s):DOI: 10.1002/cmr.a.20157
Responsible Party
Creator(s):Author: Maxime Van Landeghem
Author: Agnes Haber
Author: Jean-Baptiste D'Espinose de Lacaillerie
Author: Bernhard Blümich
Publisher:Wiley Periodicals, Inc
Topic
TR32 Topic:Other
Related Sub-project(s):A1
Subject(s):CRC/TR32 Keywords: NMR, Laplace Inversion, Porous Materials, 2D-Relaxometry
DDC: 500 Natural sciences and mathematics
File Details
File Name:2010_vanLandeghem_CMRPartA.pdf
Data Type:Text
Size(s):17 Pages
File Size:1948 kB (1.902 MB)
Date(s):Date Accepted: 2010-04-11
Mime Type:application/pdf
Data Format:PDF
Language:English
Status:Completed
Constraints
Download Permission:OnlyTR32
General Access and Use Conditions:For internal use only.
Access Limitations:For internal use only.
Licence:TR32DB Data policy agreement
Geographic
North:-no map data
East:-
South:-
West:-
Measurement Region:Laboratory
Measurement Location:--Laboratory--
Specific Informations - Publication
Status:Published
Review:PeerReview
Year:2010
Type:Article
Article Type:Journal
Source:Concepts in Magnetic Resonance Part A
Issue:3
Volume:36
Number Of Pages:17
Page Range:153 - 169
Metadata Details
Metadata Creator:Markus Küppers
Metadata Created:2013-12-02
Metadata Last Updated:2016-05-11
Subproject:A1
Funding Phase:1
Metadata Language:English
Metadata Version:V41
Dataset Metrics
Page Visits:157
Metadata Downloads:0
Dataset Downloads:0
Dataset Activity
Features